Search results for "chemistry [Carbon]"
showing 10 items of 2259 documents
SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namib…
2010
Abstract The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to per…
Resorption, growth, solid state recrystallisation, and annealing of granulite facies zircon—a case study from the Central Erzgebirge, Bohemian Massif
2005
Zircon crystals have been investigated from a gneiss area in the Central Erzgebirge, Bohemian Massif, where small occurrences/lenses of granulites (and sometimes eclogites) are located within amphibolite facies gneisses. Geological relationships indicate that leucocratic quartzofeldspathic rocks within the granulite boudins represent melts, whereas garnet-rich melanocratic rocks are considered restites, derived through multiple extraction of the leucocratic melts. The morphology of zircon crystals is quite different in these two types of granulites, with rounding pointing to higher zircon resorption in garnet-rich rocks due to multiple interaction with melts. Extensive new zircon growth can…
Age of Palaeozoic granites and metamorphism in the Tuvino-Mongolian Massif of the Central Asian Mobile Belt: loss of a Precambrian microcontinent
2001
Abstract The Tuvino-Mongolian Massif (TMM) was previously interpreted as a Precambrian block within the Central Asian Mobile Belt. According to this idea, it consists of tectonic slices composed of metamorphic rocks of pre-Mesoproterozoic basement that experienced two episodes of regional metamorphism, and Mesoproterozoic ‘cover rocks’ that were reworked together with the basement during high-grade metamorphism. Zircon U–Pb dating of granitoids from all metamorphic complexes demonstrates that the earliest metamorphic event occurred at 536±6 Ma, significantly later than the deposition of the cover rocks. Regional upper amphibolite-facies metamorphism, which affected all metasedimentary units…
Contrasting textural record of two distinct metamorphic events of similar P-T conditions and different durations
2005
A structural, metamorphic and geochronological study of the StareMesto belt implies the existence of two distinct metamorphic events of similar peak P-T conditions (700-800 � C, 8-10 kbar) during the Cambro-Ordovician and the Carboniferous tectonometamorphic events. The hypothesis of two distinct periods of metamorphism was suggested on the basis of structural discordance between an undoubtedly Carboniferous granodiorite sill intrusion and earlier Cambro-Ordovician fabrics of a banded amphibolite complex. The analysis of crystal size distribution (CSD) shows high nucleation density (N0) and low average growth rate (Gt) for Carboniferous mylonitic metagabbros and mylonitic granodiorites. The…
Intercomparison of SO2 camera systems for imaging volcanic gas plumes
2015
Abstract SO 2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO 2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO 2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO 2 cameras. In the first part of the experiment, the various technical designs are compared and the advantage…
Using calculated chemical potential relationships to account for coronas around kyanite: an example from the Bohemian Massif
2010
Corona textures around kyanite, involving for example zoned plagioclase separating kyanite from the matrix, reflect the instability of kyanite with the matrix on changing P-T conditions, commonly related to decompression. The chemical potential gradients set up between the kyanite and the matrix as a consequence of slow Al diffusion drive corona development, with the zoning of the plagioclase reflecting the gradients. Calculated mineral equilibria are used to account for corona textures involving plagioclase ± garnet around kyanite, and replacement of kyanite by plagioclase + spinel symplectite, in quartz + plagioclase + K-feldspar + garnet + kyanite granulite facies gneiss from the Blanský…
Trace metal modeling of groundwater–gas–rock interactions in a volcanic aquifer: Mount Vesuvius, Southern Italy
2005
We report a detailed study of trace metals in groundwaters from the Somma-Vesuvius volcanic complex and present a model of the chemical processes that control the fate of these components during gas–water–rock interactions. Trace metal concentrations in Vesuvian groundwaters range from 0.01 to 0.1 Ag/l for ultra-trace elements (Sb, Cs, Co, Cd, and Pb) up to 0.1–10 mg/l for minor elements (Fe and Sr), leading to water–rock ratios from ~0.5 to 10 � 9 when normalized to trace element concentrations in the host rocks. Our results indicate non-isochemical dissolution of local volcanic rocks by groundwaters, during which mobile trace elements (As, Se, Mo, V, Li) are enriched and elements such as …
Chemical and isotopic characterization of the gases of Mount Etna (Italy)
1997
Abstract In the period 1990–1995, 43 samples of dissolved gases in groundwaters (wells, springs and drainage galleries) and 64 samples of free gases (fumaroles, bubbling and soil gases) from the Mount Etna area were collected and analysed. Isotopic analyses were also carried out of both the carbon of the CO 2 in free gases and dissolved inorganic carbon (DIC) in the waters. The chemical composition of the gases depends on the relative abundances of three interacting components. These are gases of (1) atmospheric origin enriched in O 2 and N 2 , present almost exclusively in dissolved gases, (2) deep origin enriched in CO 2 , prevalent in the majority of cases, and (3) more superficial origi…
Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions
2011
A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…
Volcanic SiO2-cristobalite: A natural product of chemical vapor deposition
2020
Abstract Cristobalite is a low-pressure, high-temperature SiO2 polymorph that occurs as a metastable phase in many geologic settings, including as crystals deposited from vapor within the pores of volcanic rocks. Such vapor-phase cristobalite (VPC) has been inferred to result from silica redistribution by acidic volcanic gases but a precise mechanism for its formation has not been established. We address this by investigating the composition and structure of VPC deposited on plagioclase substrates within a rhyolite lava flow, at the micrometer to nanometer scale. The VPC contains impurities of the form [AlO4/Na+]0—coupled substitution of Al3+ charge-balanced by interstitial Na+—which are ty…